Resumo Características limnológicas de dois reservatórios foram estudadas durante os períodos seco (Agosto 2013) e de chuvas (Janeiro 2014) para avaliar a qualidade da água que abastece a cidade de Guarulhos, Brasil sudeste. Amostras de água foram coletadas em três profundidades e as características estudadas foram: alcalinidade, O2 dissolvido, CO2 livre e total, HCO3, sílica reativa solúvel e nitrogênio e fósforo dissolvido e total e clorofila-a. Transparência da água foi medida e obtidos os perfis de temperatura, pH e condutividade elétrica. Grande variabilidade sazonal e espacial das características da água ocorreu nos reservatórios. Altos valores de transparência da água, disponibilidade de CO2 livre e menores de pH, sílica reativa solúvel e nutrientes totais e dissolvidos foram documentados durante o período seco; e condições diferentes durante o período de chuvas. Os dois reservatórios foram caracterizados por baixos teores de nutrientes, clorofila-a e turbidez e alta transparência, características estas típicas de sistemas oligotróficos. Os dois reservatórios ainda permanecem sob condição de baixo impacto antropogênico e são atualmente considerados sistemas de referência para a RMSP, Região Metropolitana de São Paulo. A necessidade de ações para diminuir e até frear a entrada de nutrientes provenientes das cidades vizinhas e dos principais afluentes da bacia hidrográfica é enfatizada para manter a qualidade ecológica dos reservatórios e suas condições de referência entre os reservatórios da RMSP.

Abstract Limnological features of two reservoirs were studied in dry (August 2013) and rainy (January 2014) periods to evaluate the water quality that supply the city of Guarulhos, southeast Brazil. Water samples were collected in three depths and the following characteristics were measured: alkalinity, dissolved O2, free and total CO2, HCO3, soluble reactive silica, dissolved and total nitrogen and phosphorus, and chlorophyll-a. Water transparency was also measured and temperature, pH and electric conductivity profiles were obtained. Great seasonal and low spatial variability of the water characteristics occurred in the reservoirs. High values of water transparency, free CO2 availability, and low of pH, soluble reactive silica and total and dissolved nutrients values were recorded at the dry period, and different conditions were found at the rainy season. The two reservoirs were characterized by low nutrients, chlorophyll-a and turbidity, and high transparency, these features being typical of oligotrophic systems. The two reservoirs still remain under low anthropogenic impact conditions, and are presently considered reference systems for the SPMR, São Paulo Metropolitan Region. The need for actions that will reduce the input of nutrients from the neighboring cities and the main tributaries of the hydrographic basin is emphasized to maintain the ecological quality of the reservoirs and their reference conditions among the SPRM reservoirs.

In order to achieve better part quality in sheet metal forming the rate of the material flow into the die cavity must be efficiently controlled. This control is obtained using a restraining force supplied either by the blankholder tool, drawbeads or both. When the restraining force required is too high, the use of drawbeads is necessary, although excessive blank deformation may be produced. Some other disadvantages such as adjustment difficulties during die try-outs to determine the actual Drawbead Restraining Force (DBRF) may also be encountered. One way to solve these problems and to reduce the number of die try-outs - which are very much time consuming - is to introduce/define accurate enough drawbead concepts. The present study will make use of a method that has been developed using the similitude approach in order to understand the influence of the most important parameters on DBRF and to establish a pre-estimate DBRF theory. Data bases have been developed throughout Explicit Dynamic Finite Element Method (EDFEM) based simulations. The results are compared with experimental data bases provided by Nine (1978) and with the analytical model of Stoughton (1988) results. The average of absolute error with respect to experimental data bases was around 6% and, for the studied cases, the maximum discrepancy was found to be below 11%. For the analytical and experimental cases, the average of absolute error was approximately 5% and, for the studied cases, the maximum error was below 7%. In terms of precision, the predictions derived from this approach are adequate when compared with analytical and experimental results. For this reason, the approach has been validated and accepted as a contribution to STAMPACK®, a commercial explicit dynamic finite element based system for forming processes numerical simulation.

Restoring the internal lumen of arteries by employing an expandable mesh (stent) of metallic or polymeric material, known as angioplasty, is one of the most common procedure for treatment of the obstructive cardiovascular diseases. The stent for angioplasty have been extensively used in the treatment of the cardiovascular diseases. They should be flexible during the implant procedure and stiff when implanted into the blood vessel. These design criteria depend on the material, geometry and the technology used in the stents manufacturing. The objective of this work is to provide the optimized geometry of a stainless steel stent by means of the topological optimization technique. The general idea of this methodology is to simulate the implant process of a stent using the finite elements method, extract the sensitivities of its flexibility and stiffness and update its material distribution or topology in an iterative procedure. The algorithm for the numerical computation of the stent material distribution is based on the heuristics and in the Lagrangian of the optimization problem. The results show that the stent optimal topologies provided by this methodology have some advantages when compared with the traditional geometries of commercial stents.

A rotating cylinder reactor was designed for the synthesis of niobium carbide powders at 1173 K. Niobium carbide, NbC, was prepared by carbothermal reduction starting from commercial niobium pentoxide powders. The reactor was heated using a custom-made, two-part, hinged, electric furnace with programmable temperature control. The design and operational details of the reactor are presented. The longitudinal temperature gradient inside the reactor was determined. Total reaction time was monitored by a gas chromatograph equipped with an FID detector for determination of methane concentrations. The results show that time of reaction depended on rotation speed. NbC was also prepared in a static-bed alumina reactor using the same conditions as in the previous case. The niobium carbide powders were characterized by X-ray diffraction and compared with commercially available products. Morphological, particle size distribution and surface area analyses were obtained using SEM, LDPS and BET, respectively. Therefore, the present study offers a significant technological contribution to the synthesis of NbC powders in a rotating cylinder reactor.